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Surface Exciton-Plasmons and Optical Response of Small-Diameter Carbon Nanotubes

机译:小直径碳纳米管的表面激子等离子体和光学响应

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We study theoretically the interactions of excitonic states with surface electromagnetic modes of small-diameter (approx.<1 nm) semiconducting single-walled carbon nanotubes. We show that these interactions can result in strong exciton-surface-plasmon coupling. The exciton absorption lineshape exhibits the line (Rabi) splitting approx0.1-0.3 eV as the exciton energy is tuned to the nearest interband surface plasmon resonance of the nanotube so that the mixed strongly coupled surface plasmon-exciton excitations are formed. We discuss possible ways to bring the exciton in resonance with the surface plasmon. The exciton-plasmon Rabi splitting effect we predict here for an individual carbon nanotube is close in its magnitude to that previously reported for hybrid plasmonic nanostructures artificially fabricated of organic semiconductors deposited on metallic films. We expect this effect to open up paths to new tunable optoelectronic device applications of semiconducting carbon nanotubes.
机译:我们从理论上研究了激子态与小直径(约<1 nm)半导体单壁碳纳米管的表面电磁模式的相互作用。我们表明,这些相互作用可以导致强烈的激子-表面-等离子体耦合。激子吸收线形表现出的线(Rabi)分裂约0.1-0.3 eV,因为激子能量被调谐到纳米管的最近带间表面等离子体激元共振,从而形成了混合的强耦合表面等离子体激子激发。我们讨论了使激子与表面等离子体激元共振的可能方法。我们在这里预测的单个碳纳米管的激子-等离子体激元拉比分裂效应的强度与先前报道的由沉积在金属膜上的有机半导体人工制造的混合等离子体激元纳米结构的效应接近。我们预计这种效应将为半导体碳纳米管的新型可调光电子器件应用开辟道路。

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