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Effect of laser fluence on the characteristics of Al nanoparticles produced by laser ablation in deionized water

机译:激光注量对去离子水中激光烧蚀产生的铝纳米颗粒特性的影响

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We have studied the effects of the laser fluence on the characteristics of Al nanoparticles produced by pulsed laser ablation of Al plate in deionized water without using surfactant. Five samples of aluminum nanoparticles were synthesized by nanosecond pulsed laser ablation of a high purity aluminum plate in distilled water at five different fluences in the range of 1-3 J/cm(2). There is threshold fluence of the laser at which absorption of laser energy by water rises significantly. Absorption of the laser energy by water leads to increase oxygen atoms in the ablation medium and formation of aluminum oxide nanoparticles. By increasing the laser fluence below the threshold magnitude size of produced nanoparticles increase while by increasing the laser fluence above the threshold magnitude size of produced nanoparticles decrease. The UV-Visible-NIR absorption spectra of nanoparticles exhibit surface plasmon resonance absorption peak in the ultraviolet region. TEM and SEM micrographs are used to characterize the produced nanoparticles. The production rate of nanoparticles is increased with increasing the laser fluence.
机译:我们已经研究了激光能量密度对在不使用表面活性剂的情况下在去离子水中脉冲激光烧蚀铝板而产生的铝纳米颗粒特性的影响。通过在蒸馏水中以1-3 J / cm(2)范围内的五种不同通量对高纯度铝板进行纳秒脉冲激光烧蚀,合成了五个铝纳米颗粒样品。激光器存在阈值能量密度,在该阈值能量密度下水对激光能量的吸收显着增加。水吸收激光能量会导致烧蚀介质中的氧原子增加,并形成氧化铝纳米颗粒。通过将激光通量增加到阈值大小以下,所产生的纳米颗粒的尺寸增加,而通过将激光通量增加到阈值大小以上,所生成的纳米颗粒的尺寸减小。纳米粒子的紫外-可见-近红外吸收光谱在紫外区域表现出表面等离子体共振吸收峰。 TEM和SEM显微照片用于表征产生的纳米颗粒。纳米粒子的生产率随着激光能量密度的增加而增加。

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