Enhancing the photocatalytic degradation of salicylic acid by using molecular imprinted S-doped TiO_2 under simulated solar light

摘要

Molecular imprinted polymer coated S-dopcd TiO_2 (MIP/S-TiO_2) nanocomposites were successfully synthesized by a surface molecular imprinting technique using p-phenylenediamine as the functional monomer and salicylic acid as the template molecule. The structure and properties of the catalysts were characterized by X-ray diffraction, scanning electron microscopy, and UV-vis diffuse reflectance spectra. Compared with TiO_2 nanoparticles, the absorption edge of MIP/S-TiO_2 nanocomposites was enhanced over the whole range of visible region. Moreover, MJP/S-TiO_2 nanocomposites showed higher adsorption capacity for salicylic acid than for S-TiO_2 nanoparticles. The rate constant for the photodegradation of salicylic acid over MIP/S-TiO_2 nanocomposites was 1.7 times that of salicylic acid over S-TiO_2 nanoparticles, which was attributed to the molecular recognition ability of MlP/S-TiO_2 nanocomposites for the target molecules.