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Reply to comment on 'Photodarkening in Yb-doped aluminosilicate fibers induced by 488 nm irradiation'

机译:关于“ 488 nm辐照引起的掺Yb的铝硅酸盐纤维的光暗化”的评论答复

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摘要

In response to the Comment, we show that Engholm et al. [Opt. Lett. 33, 1216 (2008)] misinterpret the absorption peak at 230 nm and reach mistaken conclusions that contradict their experimental results. Differences in compositions and fabrication details mean that their results are only marginally relevant to our experiments [Opt. Lett. 32, 1626 (2007)]. The excitation of electrons to a charge-transfer band around 230 nm in Yb-doped aluminosilicate glasses leads to conversion from Yb~(2+) to Yb~(3+), which, in our opinion, is more likely to account for photobleaching rather than photodarkening.
机译:针对评论,我们表明Engholm等人。 [选择。来吧33,1216(2008)]误解了230 nm处的吸收峰,并得出与实验结果相矛盾的错误结论。成分和制造细节上的差异意味着它们的结果与我们的实验仅具有很小的关联性。来吧32,1626(2007)]。在掺Yb的铝硅酸盐玻璃中将电子激发到约230 nm的电荷转移带会导致从Yb〜(2+)转换为Yb〜(3+),在我们看来,这更可能是光漂白的原因。而不是光暗化。

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