Study on nonlinear kinetic and thermodynamics of oscillating reaction of amino Acid-BrO_3--Mn~(2+)-H_2SO _4-acetone system

摘要

With the help of the kinetic parameters (the rate constant (k _(in) k _p) and the apparent activation energy (E _(in) E _p) of the oscillatory induction period and oscillation period) of the oscillating reaction using thirteen amino acids, leucine (Leu), threonine (Thr), arginine (Arg), lysine (Lys), histidine (His), alanine (Ala), glutamine (Glu), glycine (Gly), methionine (Met), cystine (Cys), tryptophan (Trp), serine (Ser) and tyrosine (Tyr), as organic substrates in amino acid-BrO _3- -Mn~(2+)-H_2SO_4-acetone system, then based on the Oregonator model and the thermodynamics theory on irreversible process, the thermodynamic function (ΔH _(in), ΔG _(in), ΔS _(in) and ΔH _p, ΔG _p, ΔS _p) of these oscillating system are studied. The results indicate the entropy ΔS of these oscillating reaction are negative, thereby it is proved that the oscillating reaction is a noequilibrium system with dissipation structure in agreement with the character of the oscillating reaction from disorder to order in irreversible thermodynamics. These are satisfactorily to explain the experimental phenomena.