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首页> 外文期刊>Russian Journal of Non-Ferrous Metals >Liquid-Vapor Transformation in the Silver-Copper-Cadmium System
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Liquid-Vapor Transformation in the Silver-Copper-Cadmium System

机译:银-铜-镉体系中的液-汽相变

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The boiling-point method was used to determine the vapor pressure of cadmium over ternary liquid alloys with silver and copper at concentration ratios of 0.5 and 2.0 at T= 873-1273 K. Partial and integral ther-modynamic characteristics of temperature vs. concentration were obtained for the vapor and condensed phases. The system is characterized by a negative departure from law of ideal solutions. Using data on the boundary systems Ag-Cd and Cu-Cd, the component vapor-pressure functions were extrapolated to the high-temperature region to obtain the liquid-vapor transformation boundaries of the Ag-Cu-Cd system. The region of vapor-alloy coexistence has an upper limit at a relatively small zone where liquid silver-copper-cadmium solutions exist.
机译:在T = 873-1273 K时,使用沸点法确定镉与银和铜的三元液态合金中的蒸气压,浓度比为0.5和2.0。温度和浓度的部分和积分热力学特性分别为获得气相和冷凝相。该系统的特点是与理想解决方案的定律有负面的背离。使用关于边界系统Ag-Cd和Cu-Cd的数据,将组分蒸气压函数外推到高温区域,以获得Ag-Cu-Cd系统的液-汽相变边界。在存在液态银-铜-镉溶液的相对较小的区域中,蒸气-合金共存区域具有上限。

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