Specific features of the structures of monomeric octahedral d (2) rhenium(V) oxo complexes with oxygen atoms trans to the oxo ligands: Complexes with neutral ligands OER3 (E = P, As; R-3=Ph3, PhEt2) trans to O(oxo)

摘要

Specific features of the structures of mononuclear octahedral rhenium(V) oxo complexes with oxygen atoms of neutral ligands OER3 (E = P, As; R-3 = Ph-3, PhEt2) trans to the multiply bonded oxo ligands have been considered. The complexes contain halide ligands, as well as organic monoand bidentate ligands, in the equatorial plane. The Re-O(OER3) (trans) bonds are elongated owing to the structural manifestation of the trans influence of multiply bonded oxo ligands.