New Data on the Malonic Ester Phosphorylation

摘要

Phosphorylation reaction of malonic ester so far attracts the researchers attention that is obviously associated with a possibility of its wide chemical modifications for the synthesis of compounds with the practically useful properties. Previouslywas shown that the reaction of diethyl bromomalonate with triethyl phosphite and the reaction of diethyl chlorophosphate with sodium malonic ester proceed to afford the C-phosphorylation product.