Reactions of Bicyclo [4,1,0] heptane Derivatives with Phosphorus Pentachloride

摘要

Bicycloalkanes containing three-membered cycle possess the enhanced activity to electrophile reagents action due to raised angular and torsion strains. In this connection the study of reactions of phosphorus pentachloride with bicyclo heptane derivatives are of significant interest. We pioneered in using as a latter the easily available norcarane, 7,7-dichloro- and 2-alkoxy-7,7-dichloronorcaranes Ia-Ic.