Steric Control of Regiodirectivity of Reductive N-Vinylation-C-Phosphorylation of Pyridines with the System Alkyl Propiolate-Secondary Phosphine Oxide

Gusarova N. K.; Volkov P. A.; Ivanova N. I.; Khrapova K. O.; Albanov A. I.; Trofimov B. A.

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Steric Control of Regiodirectivity of Reductive N-Vinylation-C-Phosphorylation of Pyridines with the System Alkyl Propiolate-Secondary Phosphine Oxide

机译：丙炔酸烷基酯-次膦氧化物体系对吡啶的还原性N-维尼基化-C-磷酸化的立体定向控制

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来源
《Russian Journal of General Chemistry》 |2016年第3期|共4页
作者
Gusarova N. K.; Volkov P. A.; Ivanova N. I.; Khrapova K. O.; Albanov A. I.; Trofimov B. A.;
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正文语种 eng
中图分类化学;
关键词
pyridines; acetylenes; secondary phosphine oxides; zwitterions; 1; 2-dihydropyridines;

机译：吡啶;乙炔;仲氧化膦;两性离子;1;2-二氢吡啶;

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1. Steric Control of Regiodirectivity of Reductive N-Vinylation-C-Phosphorylation of Pyridines with the System Alkyl Propiolate-Secondary Phosphine Oxide [J] . Gusarova N. K., Volkov P. A., Ivanova N. I., Russian Journal of General Chemistry . 2016,第3期

机译：丙炔酸烷基酯-次膦氧化物体系对吡啶的还原性N-维尼基化-C-磷酸化的立体定向控制
2. Structural effect in the reductive vinylation/phosphorylation of pyridines with alkyl propiolates and secondary phosphine chalcogenides: protonation vs. zwitterion generation [J] . Nina K. Gusarova, Pavel A. Volkov, Nina I. Ivanova, Mendeleev Communications . 2017,第6期

机译：在烷基丙酸盐和仲磷酸硫氨酸的还原乙烯基化/磷酸化中的结构效应：质子化 vs 。两代生成
3. One-pot reductive N-vinylation and C(4)-phosphorylation of pyridines with alkyl propiolates and secondary phosphine chalcogenides [J] . Gusarova Nina K., Volkov Pavel A., Ivanova Nina I., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2015,第33期

机译：一锅还原N-乙烯基和吡啶与烷基丙酸酯和仲膦硫属元素化物的C（4）-磷酸化
4. Growth rate control in ALD by surface functionalization: alkyl alcohols on metal oxides [C] . Angel Yanguas-Gil, Jeffrey W. Elam Atomic layer deposition applications 6 . 2010

机译：通过表面功能化控制ALD中的生长速率：金属氧化物上的烷基醇
5. Preparations of 1,2,4-trioxanes from gamma,delta-unsaturated ketones, and reduction of alkyl silyl peroxides with catalytic quantities of phosphines. [D] . Thomas, Andrew M. 2010

机译：由γ，δ-不饱和酮制备1,2,4-三恶烷，并用催化量的膦还原烷基过氧化硅。
6. Steric hindrance controls pyridine nucleotide specificity of a flavin‐dependent NADH:quinone oxidoreductase [O] . Jacob Ball, Renata A. G. Reis, Johnson Agniswamy, 2019

机译：立体障碍控制黄素依赖性NADH：醌氧化还原酶的吡啶核苷酸特异性
7. Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates J. Am. Chem. Soc. 1998, 120, 7369−7370 [O] . Blake C. Hamann, John F. Hartwig 1998

机译：在空间阻碍螯合烷基膦提供芳基碘化物，溴化物和氯化物的钯催化胺化的大型速率加速，以及芳基甲苯基酸酯J.AM的第一胺化。化学。 SOC。 1998,120,7369-7370
8. Chiral Synthesis via Organoboranes. 22. Selective Reductions. 44. The Effect of the Steric Requirements of the Alkyl Substituent in Isopinocampheylalkylchloroboranes for the Asymmetric Reduction of Representative Ketones [R] . Brown, H. C., Srebnik, M., Ramachandran, P. V. 1989

机译：有机硼烷的手性合成。 22.选择性削减。 44.异丙基氨基烷基氯硼烷中烷基取代基的空间要求对代表性酮的不对称还原的影响

Steric Control of Regiodirectivity of Reductive N-Vinylation-C-Phosphorylation of Pyridines with the System Alkyl Propiolate-Secondary Phosphine Oxide

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