~1H NMR Study of cis-trans Isomerization of Rhenium(III) Binuclear Complexes in Acetone Solutions

V. A. Mikhalev

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~1H NMR Study of cis-trans Isomerization of Rhenium(III) Binuclear Complexes in Acetone Solutions

机译：丙酮溶液中（（III）双核配合物的顺反异构化〜1H NMR研究

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The behavior of rhenium(III) binulcear complexes K_2Re_2Hlg_8 and Re_2(RCOO)_2Hlg_4 [Hlg = Cl and Br; R = CH_3, C_2H_5, (CH_3)_2CH, and (CH_3)_3C] in acetone solutions was studied by ~1H NMR. Reaction with neutral donor ligand (H_2O and hexamethylphosphoramide) induces transformation of trans-Re_2(RCOO)_2Hal_4 to solvated cis-Re_2(RCOO)_2Hal_4.

机译：bin（III）双核配合物K_2Re_2Hlg_8和Re_2（RCOO）_2Hlg_4的行为[Hlg = Cl和Br;通过〜1 H NMR研究了丙酮溶液中的R = CH_3，C_2H_5，（CH_3）_2CH和（CH_3）_3C]。与中性供体配体（H_2O和六甲基磷酰胺）反应诱导反式Re-Re_2（RCOO）_2Hal_4转化为溶剂化的cis-Re_2（RCOO）_2Hal_4。

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《Russian Journal of General Chemistry》 |2001年第1期|共3页
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V. A. Mikhalev;
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1. ~1H NMR Study of cis-trans Isomerization of Rhenium(III) Binuclear Complexes in Acetone Solutions [J] . V. A. Mikhalev Russian Journal of General Chemistry . 2001,第1期

机译：丙酮溶液中（（III）双核配合物的顺反异构化〜1H NMR研究
2. 1H and 13C-NMR and molecular dynamics studies of cyclosporin a interacting with magnesium(II) or cerium(III) in acetonitrile. Conformational changes and cis-trans conversion of peptide bonds. [J] . Bernardi F, Gaggelli E, Molteni E, Biophysical Journal . 2006,第4期

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3. Combined high resolution NMR and ~1H and ~(17)O relaxometric study sheds light on the solution structure and dynamics of the Lanthanide(III) complexes of HPDO3A [J] . Delli Castelli D., Caligara M.C., Botta M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2013,第12期

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4. STUDY OF FULVIC-ALUMINUM(III) ION COMPLEXES BY ~(27)AL SOLUTION NMR [C] . Norman C.Y. Lee, David K. Ryan Biennial Conference of the International Humic Substances Society;Humic Substances Seminar . 2004

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5. 1- and 2-dimensional proton, carbon-13, and platinum-195 NMR studies of platinum(EDTA) dichloride in heavy water solution and structural characterization of several iron(III) tris(2-pyridylmethyl)amine complexes. [D] . Mullaney, Matthew. 1996

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6. 1H and 13C-NMR and Molecular Dynamics Studies of Cyclosporin A Interacting with Magnesium(II) or Cerium(III) in Acetonitrile. Conformational Changes and cis-trans Conversion of Peptide Bonds [O] . Francesca Bernardi, Elena Gaggelli, Elena Molteni, 2006

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7. 1H and 13C-NMR and Molecular Dynamics Studies of Cyclosporin A Interacting with Magnesium(II) or Cerium(III) in Acetonitrile. Conformational Changes and cis-trans Conversion of Peptide Bonds [O] . Bernardi, Francesca, Gaggelli, Elena, Molteni, Elena, 2006

机译：乙腈中与镁（II）或铈（III）相互作用的环孢菌素A的1H和13C-NMR和分子动力学研究。肽键的构象变化和顺反转换

~1H NMR Study of cis-trans Isomerization of Rhenium(III) Binuclear Complexes in Acetone Solutions

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