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首页> 外文期刊>Russian Journal of General Chemistry >Study of the State of Uranogermanates M~(II)(HGeUO6)2-6H2O in Aqueous Solutions (M~(II);.= Mn, Co, Ni, Cu, Zn)
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Study of the State of Uranogermanates M~(II)(HGeUO6)2-6H2O in Aqueous Solutions (M~(II);.= Mn, Co, Ni, Cu, Zn)

机译:水溶液(M〜(II);。= Mn,Co,Ni,Cu,Zn)中尿烷锗酸盐M〜(II)(HGeUO6)2-6H2O的状态研究

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摘要

The state of d-elements uranogermanates M~(II)(HGeUO6)2-6H2O in aqueous salt solutions in a wide range of ionic strength, ionic composition, and acidity has been investigated. The pH ranges of the uranogermanates stability have been determined, and products of their transformation have been identified. Solubility, solubility equilibrium constant, and Gibbs energy of formation have been determined for the studied uranogermanates. Diagrams of uranium(VI), germanium(IV), and M(II) state in aqueous solutions and in equilibrium solid phases have been plotted.
机译:研究了在离子强度,离子组成和酸度范围很广的盐水溶液中d-元素尿酸锗酸盐M〜(II)(HGeUO6)2-6H2O的状态。已经确定了尿精锗酸盐稳定性的pH范围,并且已经鉴定了其转化的产物。已确定了所研究的铀锗酸盐的溶解度,溶解度平衡常数和吉布斯形成能。绘制了水溶液和平衡固相中铀(VI),锗(IV)和M(II)的状态图。

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