Biacetyl Monooxime Ferrocenoylhydrazone and Its Complexing Properties

摘要

Biacetyl monooxime ferrocenoylhydrazone has been synthesized and studied by H-1 NMR, IR, and electronic spectroscopy. The electronic absorption spectrum of the title compound in the UV and visible regions has been found to depend on the solvent polarity and pH. Most favorable structures of the hydrazone in solution and gas phase have been determined by quantum chemical calculations. The complexing ability of biacetyl monooxime ferrocenoylhydrazone toward copper(II), nickel(II), and zinc(II) ions has been estimated.