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首页> 外文期刊>Russian Journal of General Chemistry >Sructural Parameters of the Nearest Surrounding of Tri- and Tetravalent Actinide Ions in Aqueous Solutions of Actinide Salts
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Sructural Parameters of the Nearest Surrounding of Tri- and Tetravalent Actinide Ions in Aqueous Solutions of Actinide Salts

机译:in系元素盐水溶液中最近的三价和四价I系元素离子周围结构参数

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摘要

Published data are generalized on different research methods for structural characterization of the nearest surrounding of trivalent and tetravalent actinide ions in aqueous solutions of their salts under standard conditions. The structural parameters such as coordination numbers, interparticle distances, the parameters of the second coordination sphere, and the types of ionic association are discussed. The quantitative characteristics of hydrated complexes of poorly known trivalent actinide ions are determined on the basis of comparative analysis with lanthanide ions.
机译:在标准条件下,其盐水溶液中三价和四价act系离子最接近的周围结构表征的不同研究方法,对已发表的数据进行了概括。讨论了结构参数,例如配位数,粒子间距离,第二配位球的参数以及离子缔合的类型。在与镧系元素离子进行比较分析的基础上,确定了鲜为人知的三价act系元素离子水合配合物的定量特征。

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