Reactivity of Amphiphilic Calix [4] resorcinolarenes and Phenols in the Reverse Micellar System Sodium Bis (2-ethylhexyl) Sulfosuccinate-Decane-Water

摘要

The mechanism of reaction of calix [4] resorcinolarene, aminomethylated calix [4] resorcinolarene, and 2-(dimethylaminomethyl)-4-isononylphenol with ethyl 4-nitrophenyl (chloromethyl) phosphonate in the reverse micellar system anionic surfactant-sodium bis(2-ethylhexyl) sulfosuccinate-decane-water changes compared with direct micellar systems and aqueous-organic solutions. It was shown that the calix[4] resorcinol-arenes and phenol studied increase the percolation threshold of the system.