Synthesis and Structure of mu-Peroxybis [(4-bromophenoxy)tri(p-tolyl)antimonyl]

摘要

Organoantimony compounds containing Sb-O-O-C bonds have been reported [1,3], but only one compond with antimony atoms intervened by peroxy bridges is known [4]. The structure of the latter was established by X-ray diffraction. It was shown that four antimony aotms are bound with each other by four oxygen and two peroxy bridges. Binculear antimony compounds with a peroxy group between two antimony atoms have been unknown up to now.