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Study on Aromatic Enrichment of FCC Slurry for Synthesizing COPNA

机译:FCC浆液的芳烃富集合成COPNA的研究

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Fourier Transform Infra red Spectroscopy (FT-IR),Proton Nuclear Magnetic Resonance (~1H-NMR),Carbon 13 Nuclear Magnetic Resonance (~(13)C-NMR) and group compositional analysis were used to characterize the synthesis reaction of fluidized catalytic cracking (FCC) slurry before and after solvent extraction treatment.This investigation provided a great deal of critical information for use in future process development.Before solvent extraction,the FCC slurry is extremely complex.Saturates content is relatively high and there are a variety of aromatic ring substituents.Also,molecular uniformity is poor and chemical steric hindrance is strong.On the contrary,the composition of a fraction enriched in aromatics is relatively simple with excellent uniformity and homogeneous molecular alkyl substituents.The aromatic enriched fraction (FCCRF) from the FCC slurry has weak chemical steric hindrance and,consequently,is more reactive than the original FCC slurry.
机译:傅里叶变换红外光谱(FT-IR),质子核磁共振(〜1H-NMR),碳13核磁共振(〜(13)C-NMR)和基团组成分析用于表征流化催化合成反应裂化(FCC)浆液在溶剂萃取处理之前和之后进行。这项研究为将来的工艺开发提供了大量重要信息。在溶剂萃取之前,FCC浆液非常复杂。饱和物含量相对较高,并且存在多种另外,分子均一性差并且化学位阻强。相反,富含芳族化合物的馏分的组成相对简单,具有优异的均匀性和均一的分子烷基取代基。来自芳族化合物的芳族化合物的富集馏分(FCCRF) FCC浆液的化学空间位阻较弱,因此比原始FCC浆液更具反应性。

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