Non-classical structures of organic compounds;unusual stereochemistry and hypercoordination

摘要

Non-classical structures of organic compounds are defined as molecules containing non-tetrahedral tetracoordinate and/or hypercoordinate carbon atoms.The evolution of the views on this subject is considered and the accumulated theoretical and experimental data on the structures and dynamic transformations of non-classicalorganic compounds and the software potential of modern quantum chemistry has now acquired high predictive capacity and is the msot important source of data on the structures of non-classical compounds.The bibliography includes 227 references.