Human slip on smooth surfaces is a common accident, even though the footwear soling materials are designed with cleats and treads to provide more friction with the floor. About 20% of footwear is made with thermoplastic rubber (TPR; styrene-butadiene-styrene) soles. The slip resistance property under wet-flooring conditions of this kind of sole is poor because of the nonionic nature of the polymer. Chemical surface modification can be exploited to improve the slip-resistance property of TPR soles. The surface is chemically modified with trichloroisocyanuric acid in a methyl ethyl ketone medium (TCI/MEK; at 1, 2, and 3%) to introduce chlorinated and oxidized moieties to the rubber surface. The extent of surface modification produced in TPR with this change can be tested using attenuated total reflectance Fourier transform infrared spectroscopy, scanning electron microscopy, and contact angle and surface roughness measurements. The improvement in slip resistance can be evaluated by measuring the coefficient of friction using a dynamic slip-resistance tester. The extent of the change in the functional physical properties, such as surface roughness, contact angle, work adhesion, in slip resistance can be improved by optimizing the concentration of trichloroisocyanuric acid. Physicomechanical properties of unmodified and modified soles that are essential for wear performance can be tested and compared. Quantitative changes on the surface of modified rubber soles increases surface roughness, reduces contact angles, and increases work energy, so there is a considerable increase in the coefficient of friction, especially under wet floor conditions. The chemical surface treatment tends to reduce the bulk mechanical properties, such as tensile strength, elongation at break, and abrasion resistance, because cyanuric acid attacks the sole. The coefficient of friction produces a positive trend at 1 and 2% TCI/MEK treatments, but the trend is negative at a 3% concentration. The optimum surface treatment level for surface modification to enhance the slip resistance of TPR is 2% TCI/MEK.
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