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Vanadium doping of strontium germanate and their visible photocatalytic properties

机译:钒酸锗锶的掺杂及其可见光催化性能

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摘要

Vanadium-doped strontium germanate with rod-shaped morphology and different vanadium contents has been synthesized by a facile hydrothermal process. The obtained vanadium-doped strontium germanate has been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and ultraviolet (UV) diffuse reflectance spectra. The phase of the vanadium-doped strontium germanate depends on the vanadium content. SEM observations show that the vanadium-doped strontium germanate comprises a rod-shaped morphology with diameter and length of nanoscale/microscale size and longer than 10 mm, respectively. The band gap of the vanadium-doped strontium germanate depends on the vanadium content and increases significantly from 2.74 eV to 3.02 eV with the vanadium content increasing from 1 wt% to 10 wt%. Vanadium-doped strontium germanate shows highly efficient photocatalytic activity for the degradation of methylene blue under sunlight irradiation. The results show that vanadium-doped strontium germanate is very promising for visible-light photocatalytic applications.
机译:通过简便的水热法合成了具有棒状形态和不同钒含量的钒掺杂锗酸锶。通过X射线衍射(XRD),扫描电子显微镜(SEM)和紫外(UV)漫反射光谱对所得的钒掺杂锗酸锶进行了表征。钒掺杂锗酸锶的相取决于钒含量。 SEM观察表明,掺杂钒的锗酸锶具有杆状形态,其直径和长度为纳米级/微米级,并且长于10mm。钒掺杂锗酸锶锶的带隙取决于钒含量,并且从2.74 eV显着增加到3.02 eV,钒含量从1 wt%增加到10 wt%。钒掺杂锗酸锶在阳光照射下对亚甲基蓝的降解显示出高效的光催化活性。结果表明,钒掺杂锗酸锶对于可见光光催化应用非常有前途。

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