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Influence of piezoelectric effect on dissolving behavior and stability of ZnO microanowires in solution

机译:压电效应对ZnO微纳米线在溶液中的溶解行为和稳定性的影响

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We demonstrate for the first time the corrosion behavior of ZnO microanowires under stress. The influence of the piezoelectric effect on the corrosion of ZnO microanowires in acidic and alkaline environments was investigated. The two sides of the bent ZnO microanowires have a significantly different corrosion rate while strain-free ZnO microanowires remain the same. Corrosion behaviors of individually bent ZnO microwires (MWs) have been clearly observed under various strains estimated using the local curvature model. The corrosion phenomena of bent ZnO MWs in acidic and alkaline environments were different. The outer surface of the wire attracts free hydroxide ions and the inner one attracts hydrogen ions from the solution which promotes the chemical reaction due to the effect of the piezoelectric potential which is generated by strain. The experimental results indicated that the corrosion rate is quite sensitive to strain, which provides a recommendation for the design and evaluation of nanodevices that serve in extreme environments.
机译:我们首次证明了ZnO纳米线在应力作用下的腐蚀行为。研究了在酸性和碱性环境中压电效应对ZnO微纳米线腐蚀的影响。弯曲的ZnO微米/纳米线的两侧具有明显不同的腐蚀速率,而无应变的ZnO微米/纳米线保持相同。在使用局部曲率模型估计的各种应变下,可以清楚地观察到单独弯曲的ZnO微丝(MWs)的腐蚀行为。弯曲的ZnO MWs在酸性和碱性环境下的腐蚀现象不同。导线的外表面吸引自由的氢氧根离子,内表面吸引溶液中的氢离子,这是由于应变产生的压电势的作用,从而促进了化学反应。实验结果表明腐蚀速率对应变非常敏感,这为在极端环境下工作的纳米器件的设计和评估提供了建议。

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