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Pre-irradiation induced emulsion graft polymerization of acrylonitrile onto polyethylene nonwoven fabric

机译:辐射前诱导的丙烯腈在聚乙烯无纺布上的乳液接枝聚合

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摘要

Acrylonitrile has been widely used in the modification of polymers by graft polymerization. In the present work, pre-irradiation induced emulsion graft polymerization method is used to introduce acrylonitrile onto PE nonwoven fabric instead of the traditional reaction in organic solvents system. The degree of grafting (DC) is measured by gravimetric method and the kinetics of the graft polymerization is studied. The existence of the graft chains is proven by Fourier transform infrared spectroscopy (FT-IR) analysis. Thermal stability of the grafted polymer is measured by Thermogravimetric analysis (TGA).
机译:丙烯腈已被广泛用于通过接枝聚合反应对聚合物进行改性。在目前的工作中,代替有机溶剂体系中的传统反应,采用预辐照乳液接枝聚合法将丙烯腈引入到PE无纺布上。用重量法测定接枝度(DC),并研究了接枝聚合反应的动力学。嫁接链的存在已通过傅立叶变换红外光谱(FT-IR)分析得到证明。接枝聚合物的热稳定性通过热重分析(TGA)测量。

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