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Radon capture with silver exchanged zeolites

机译:用银交换沸石捕获

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摘要

To enable laboratory work with larger amounts of ~(226)Ra and its decay products, e.g., ~(222)Rn and its daughters, these need to be captured in order to avoid unnecessary alpha contamination of the laboratory work space and ventilation systems.In this study, radon gas was pumped through a column filled with the silver exchanged zeolite called "silver ex-changed molecular sieves 13X" (Ag_(84)Na_2[RAl_O2)_(86)(SiO_2)_(106)]. xH_2O). After exposure to radon, the radioactivity of the zeolite was measured repeatedly using high resolution gamma spectrometry. It was shown that radon was captured and retained in the silver exchanged zeolite. The zeolites' ability to retain radon was decreased by formation of metallic silver, caused by ionizing radiation. However, the zeolite was regenerated by heating and its radon capture ability was restored. The daughters of radon are not in gas phase and will hence stay on the column.
机译:为了使实验室工作能够使用大量的〜(226)Ra及其衰变产物,例如〜(222)Rn及其子代,必须将其捕获,以避免对实验室工作空间和通风系统造成不必要的α污染。在这项研究中,ra气被泵送通过装有银交换沸石的柱子,该柱子被称为“银交换分子筛13X”(Ag_(84)Na_2 [RAl_O2)_(86)(SiO_2)_(106)]。 xH_2O)。暴露于ra后,使用高分辨率伽马能谱法重复测量沸石的放射性。结果表明ra被捕获并保留在银交换的沸石中。由于电离辐射的形成,金属银的形成降低了沸石保留ra的能力。然而,通过加热使沸石再生,并且恢复了其ra捕获能力。 ra的子代不在气相中,因此将留在色谱柱上。

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