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Red luminescence from potassium feldspar for dating applications: a study of some properties relevant for dating

机译:钾长石的红色发光用于约会应用:与约会有关的一些特性的研究

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Aspects of the red thermoluminescence (RTL) and IR (833 +/- 5 nm) stimulated red (lambda(emission) = 600-750 nm) luminescence (orange-red IRSL) of potassium feldspar from different origins are described. Anomalous fading of RTL (300-500degreesC) from a selection of potassium feldspar samples was tested. High temperature RTL (300-450degreesC) exhibits less anomalous fading in comparison to UV luminescence, for the samples under study. The result supports the contention of Zink and Visocekas (1997) that the red TL emission from feldspar does not fade. It was found that RTL is bleachable due to IR exposure, and the relationship between RTL lost and orange-red IRSL produced is linear. It is shown that around one third of the trapped charge responsible for the orange-red IRSL signal gives rise to an RTL signal, indicating that some traps and luminescence centres are shared for RTL and orange-red IRSL. Specific characteristics of orange-red IRSL from feldspar were identified. It was found that the orange-red IRSL decay curve is bleachable by IR and daylight and can be described by the sum of three exponential components. Orange-red IRSL fading was tested. Short-term storage tests (up to 2 weeks) showed no fading. Longer-term (ca. months) storage of orange-red IRSL do in fact indicate fading, though at levels considerably lower than for the UV emission. The contradictory result is possibly due to the detection wavelength. As such, it is highly likely that the long-term fading experiment is strongly influenced by the feldspar emission centred at ca. 570 nm, which exhibits anomalous fading, while the short-term fading experiment is more greatly influenced by the far red emission centred at ca. 710 nm that in comparison to UV emission shows no or less fading. (C) 2003 Elsevier Ltd. All rights reserved. [References: 34]
机译:描述了来自不同来源的钾长石的红色热致发光(RTL)和IR(833 +/- 5 nm)激发的红色(λ(发射)= 600-750 nm)发光(橙红色IRSL)的方面。测试了从钾长石样品中选择的RTL(300-500°C)的异常褪色。对于正在研究的样品,与UV发光相比,高温RTL(300-450℃)表现出更少的异常褪色。结果支持Zink和Visocekas(1997)的观点,长石的红色TL发射不会褪色。已经发现,由于IR暴露,RTL是可漂白的,并且RTL损失与产生的橙红色IRSL之间的关系是线性的。结果表明,负责橙红色IRSL信号的捕获电荷中约有三分之一会产生RTL信号,这表明RTL和橙红色IRSL共享了一些陷阱和发光中心。确定了长石橙红色IRSL的特定特征。结果发现,橙红色的IRSL衰减曲线可以被IR和日光所漂白,并且可以通过三个指数成分的总和来描述。测试了橙红色IRSL褪色。短期存储测试(长达2周)显示没有褪色。橙红色IRSL的长期保存(约数月)确实表明褪色,尽管其含量远低于UV辐射的含量。矛盾的结果可能是由于检测波长。因此,长期衰落的实验很有可能受到以ca为中心的长石辐射的强烈影响。 570 nm,表现出异常的衰落,而短期衰落实验则受到以ca为中心的远红色发射的更大影响。在710 nm处,与UV发射相比,没有或几乎没有褪色。 (C)2003 Elsevier Ltd.保留所有权利。 [参考:34]

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