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Synthesis and fluorescence properties of 7-hydroxy-3- (2-pyridyl)coumarin derivatives

机译:7-羟基-3-(2-吡啶基)香豆素衍生物的合成及荧光性质

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摘要

Three coumarin derivatives, 7-hydroxy-3-(2-pyridyl)coumarin (HPC), 7-(4-(5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl)benzyloxy)-3-(2-pyridyl)coumarin (Ox-PC), and 7-(4-(9H-carbazol-9-yl)butoxy)-3-(2-pyridyl)coumarin (Cz-PC), were synthesized and characterized by elemental analysis, ~1H NMR, FT-IR, and UV–vis absorption spectra. The fluorescence behaviors of the compounds in methanol solutions and solid states were investigated. HPC exhibits weak green emission, whereas Cz-PC and Ox-PC show strong blue emissions in dilute solutions.
机译:三种香豆素衍生物,7-羟基-3-(2-吡啶基)香豆素(HPC),7-(4-(5-(4-叔丁基苯基)-1,3,4-恶二唑-2-基)苄氧基)合成了-3-(2-吡啶基)香豆素(Ox-PC)和7-(4-(9H-咔唑-9-基)丁氧基)-3-(2-吡啶基)香豆素(Cz-PC)并通过元素分析,〜1H NMR,FT-IR和UV-vis吸收光谱进行表征。研究了该化合物在甲醇溶液和固态中的荧光行为。 HPC在稀溶液中显示出弱绿色发射,而Cz-PC和Ox-PC在显示中显示强蓝色发射。

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