EFFECTS OF ORGANIC SOLVENT ADDITION ON THE EPOXIDATION OF PROPENE CATALYZED BY TS-1

Zhaoguang Zhang; Jingna Kang; Yaquan Wang

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EFFECTS OF ORGANIC SOLVENT ADDITION ON THE EPOXIDATION OF PROPENE CATALYZED BY TS-1

机译：有机溶剂的添加对TS-1催化丙烯环氧化反应的影响

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Effects of organic solvent addition on the epoxidation of propene catalyzed by TS-1 were studied. It was found that addition of 1,2-dichloroethane to the reaction increased not only the conversion and utilization efficiency of H2o2, but also the selectivity to PO. The origin of the effects was studied through the characterization of the catalysts after the reaction and the influence of organic solvents on the decomposition of H2O2 and PO.

机译：研究了有机溶剂的添加对TS-1催化丙烯环氧化反应的影响。发现向反应中添加1，2-二氯乙烷不仅增加了H 2 O 2的转化和利用效率，而且还提高了对PO的选择性。通过反应后催化剂的表征以及有机溶剂对H2O2和PO分解的影响，研究了影响的起因。

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《Reaction kinetics & catalysis letters》 |2007年第1期|共6页
作者
Zhaoguang Zhang; Jingna Kang; Yaquan Wang;
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正文语种 eng
中图分类化学动力学、催化作用;
关键词
Propene; propene oxide; TS-1; 1; 2-dichloroethane;

机译：丙烯;环氧丙烷;TS-1;1;2-二氯乙烷;

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专利

1. Effects of organic solvent addition on the epoxidation of propene catalyzed by TS-1 [J] . Zhaoguang Zhang, Jingna Kang, Yaquan Wang Reaction Kinetics and Catalysis Letters . 2007,第1期

机译：有机溶剂的添加对TS-1催化丙烯环氧化的影响
2. Au/uncalcined TS-1 catalysts for direct propene epoxidation with H-2 and O-2: Effects of Si/Ti molar ratio and Au loading [J] . Feng Xiang, Duan Xuezhi, Yang Jia, Chemical engineering journal . 2015,第Null期

机译：用于H-2和O-2的直接丙烯环氧化的Au /未煅烧TS-1催化剂：Si / Ti摩尔比和Au负载量的影响
3. Au/TS-1 catalyst prepared by deposition-precipitation method for propene epoxidation with H-2/O-2: Insights into the effects of slurry aging time and Si/Ti molar ratio [J] . Feng Xiang, Duan Xuezhi, Cheng Hongye, Journal of Catalysis . 2015,第Null期

机译：沉积-沉淀法制备的Hu / H-2丙烯环氧化丙烯制Au / TS-1催化剂：研究浆料老化时间和Si / Ti摩尔比的影响
4. Research on Effects of Solvents on Propylene Epoxidation with the TS-1 Catalyst [C] . Lina Wang International Conference on Machinery, Materials and Computing Technology . 2017

机译：溶剂对TS-1催化剂丙烯环氧化溶剂的影响研究
5. Gas-phase epoxidation of propylene over gold/TS-1 catalysts. [D] . Taylor, Bradley Martin. 2005

机译：金/ TS-1催化剂上丙烯的气相环氧化。
6. Promotion of the lipase-catalyzed hydrolysis of conjugated linoleic acid l-menthyl ester by addition of an organic solvent [O] . Takashi Kobayashi, Toshihiro Nagao, Yomi Watanabe, -1

机译：通过添加有机溶剂促进脂肪酶催化的共轭亚油酸1-薄荷酯的水解
7. The effects of impregnation of precious metals on the catalytic activity of titanium silicate (TS-1) in epoxidation of propene using hydrogen peroxide [O] . Shin, SB, Lee, D-W, Chadwick, D 2016

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EFFECTS OF ORGANIC SOLVENT ADDITION ON THE EPOXIDATION OF PROPENE CATALYZED BY TS-1

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