Solvothermal in situ ligand synthesis, crystal structure and fluorescent properties of a new heterocyclic compound 1,1 '-bis{3-(pyridin-2-yl)H-imidazo[1,5-a]pyridine}

摘要

Solvothermal in situ ligand reaction of bis(2-pyridinylmethyl)amine (bpa) in the presence of Fe(ClO4)(2) (.) 6H(2)O and NaN3 yielded the crystalline fluorescent organic heterocyclic compound 1, 1'-bis{3(pyridin-2-yl)H-imidazo[1, 5-a]pyridine} 1 and the byproduct Fe(bPa)(2)(ClO4)(2) 2. Compound I is the first example of imidazo[1, 5-a]pyridine compound synthesized by in situ reaction under solvothermal conditions.