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Cobalt catalysts derived from hydrotalcite-type precursors applied to steam reforming of ethanol

机译:衍生自水滑石型前驱体的钴催化剂,用于乙醇的蒸汽重整

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摘要

Catalysts derived from Co/Mg/Al hydrotalcite-type precursors modified with La and Ce were characterized by XANES and tested in ethanol steam reforming. The reaction data showed that, with a molar ratio of water: ethanol = 3:1 in the feed, addition of Ce and La favored acetaldehyde production. Increasing the water content (water:ethanol = 5:1) decreased the acetaldehyde formation by favoring the adsorption of water molecules on these samples, enhancing the acetaldehyde conversion.
机译:用XANES对由La和Ce改性的Co / Mg / Al水滑石型前体衍生的催化剂进行了表征,并在乙醇蒸汽重整中进行了测试。反应数据表明,在进料中水:乙醇= 3∶1的摩尔比下,Ce和La的加入有利于乙醛的产生。增加水分含量(水:乙醇= 5:1)可以通过促进水分子在这些样品上的吸附来减少乙醛的形成,从而提高乙醛的转化率。

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