Synthesis of zeolitic-type adsorbent material from municipal solid waste incinerator bottom ash and its application in heavy metal adsorption

摘要

Municipal solid waste incinerator (MSWI) bottom ash (BA) was converted to zeolitic-type adsorbent materials by hydrothermal conversion under strongly alkaline conditions. The conversion product was determined to be a mixture of sodium aluminum silicate hydrate (SASH) (Na20·AI203·1.68Si02·1.73H2O) and tobermorite (Ca5Si60_(16)(OH)2·4H2O). The BET specific surface area was 22.1 m~2/g, which represented a significant gain compared to the BA (4.6m~2/g) due to the formation of micropores and mesopores. The converted BA demonstrated promising performance for application as a sorbent towards several heavy metals (oxyanions of As(V), and Cd~(2+), Co~(2+), Ni~(2+), Pb~(2+), and Zn~(2+)). Its performance was found to be generally superior to that of a mainly clinoptilolite natural zeolite, achieving greater sorption extents and better stabilizing capability of contaminated sediments. At a lower dosage rate (50 mg sorbent per gram sediment) to that of natural zeolite, converted BA achieved greater than 80% reduction of cationic heavy metal concentrations in sediment porewater. These results suggest a promising route for reutilization of MSWI-BA, which can greatly enhance the sustainability of waste incineration technology.