Membrane processes for effective methanol synthesis in the forest based biorefinery

摘要

ZSM-5 membranes were prepared and their performance for methanol separations from synthesis gas was evaluated. The experimentally observed permeances at room temperature for the ZSM-5 membranes were 0.3,1,12 and 18 x 10~(-7) molm~(-2) s~(-1) Pa~(-1) for H2, CO2, CH3OH and H2O, respectively, which resulted in a separation factor a methanol/H2 of about 30. For a stoichiometric feed, the one pass CO_x-conversion for a traditional methanol process is about 26% per pass, which requires a recirculation loop with the associated disadvantages. By assuming that the same membrane performance could be obtained at industrial conditions, it was shown by mathematical modeling that a ZSM-5 membrane reactor could reach 97% CO_x-conversion per pass, while a ZSM-5 membrane module process could reach 81 % conversion per pass for a stoichiometric feed. As a result of the high conversion per pass for the membrane processes, one pass design with the associated advantages is possible for these processes. A membrane module based system is preferable over a membrane reactor of practical reasons. However, similar performance to the membrane processes can of course be achieved with a one pass process comprised of a series of methanol reactors, reactor effluent heat exchangers, coolers and condensers.