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Hydrogen Permeation in Plastically Deformed Steel Membranes

机译:塑性变形钢膜中的氢渗透

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We study the influence of plastic deformation on the electrochemical permeability of hydrogen. For this purpose, membrane specimens of FeE690T steel were deformed in the cold state by rolling or tension, and the diffusion of hydrogen in these specimens was measured by the classical Devanathan-Stachursky technique. The effective diffusion coefficients are determined according to the time dependences of the intensity of hydrogen flow from the back side of the membrane. They are characterized by the well-pronounced dependence on the level of strain. Moreover, the diffusion of hydrogen is simulated by taking into account the phenomenon of seizure of hydrogen atoms by traps formed in the presence of plastic strains. The linear diffusion equation is used to compute the time dependence of permeation of hydrogen for various densities of the traps. The effective coefficients of hydrogen diffusion are determined from the permeation curves. The accumulated results are in good agreement with the experimental data.
机译:我们研究了塑性变形对氢的电化学渗透性的影响。为此目的,FeE690T钢的膜试样在冷态下会因滚动或拉伸而变形,并通过经典的Devanathan-Stachursky技术测量氢在试样中的扩散。有效扩散系数根据氢从膜背面流出的强度的时间依赖性来确定。它们的特征是对应变水平的明显依赖。此外,通过考虑在塑性应变的存在下形成的陷阱对氢原子的吸附现象来模拟氢的扩散。线性扩散方程用于计算阱的各种密度下氢渗透的时间依赖性。氢扩散的有效系数由渗透曲线确定。累积结果与实验数据吻合良好。

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