A New Type of Methacrylate-Substituted Oxozirconium Clusters: [Zr_3O(OR)-5(OMc)_5]_2 and [Zr_3O(OR)_3(OMc)_7]_2

Bogdan Moraru; Silvia Gross; Guido Kickelbick; Gregor Trimmel; Ulrich Schubert

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A New Type of Methacrylate-Substituted Oxozirconium Clusters: [Zr_3O(OR)-5(OMc)_5]_2 and [Zr_3O(OR)_3(OMc)_7]_2

机译：一种新型的甲基丙烯酸酯取代的氧锆簇：[Zr_3O（OR）-5（OMc）_5] _2和[Zr_3O（OR）_3（OMc）_7] _2

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The new clusters Zr_6o_2(OBu)_10(OMc)_10 and Zr_6O_2(OMe)_4(OBu)_2(OMc)_14 were prepared from Zr(OBu)_4 and methacrylic acid. For the preparation of Zr_6O_2(OMe)_4(OBu)_2(OMc)_14, partial exchange of the butoxy groups is necessary. The custers consist of two Zr_3 subunits that dimerize via alkoxide bridges. The structures are of the same type, except that four terminal butoxy ligands in Zr_6O_2(OBu)_10(OMc)_10 are exchanged for chelating methacrylate ligands in Zr_6O_2(OMe)_4(OBu)_2(OMc)_14.

机译：由Zr（OBu）_4和甲基丙烯酸制备新的簇Zr_6o_2（OBu）_10（OMc）_10和Zr_6O_2（OMe）_4（OBu）_2（OMc）_14。为了制备Zr_6O_2（OMe）_4（OBu）_2（OMc）_14，丁氧基的部分交换是必要的。刺突由两个Zr_3亚基组成，它们通过醇盐桥二聚。该结构具有相同的类型，只是将Zr_6O_2（OBu）_10（OMc）_10中的四个末端丁氧基配体交换为螯合Zr_6O_2（OMe）_4（OBu）_2（OMc）_14中的甲基丙烯酸酯配体。

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来源
《Monatshefte fur Chemie》 |2001年第9期|共7页
作者
Bogdan Moraru; Silvia Gross; Guido Kickelbick; Gregor Trimmel; Ulrich Schubert;
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正文语种 eng
中图分类化学;
关键词
clusters; X-ray structure determination; zirconium; carboxylates; metal alkxodies;

机译：团簇;X射线结构测定;锆;羧酸盐;金属醇;

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1. A New Type of Methacrylate-Substituted Oxozirconium Clusters: [Zr_3O(OR)-5(OMc)_5]_2 and [Zr_3O(OR)_3(OMc)_7]_2 [J] . Bogdan Moraru, Silvia Gross, Guido Kickelbick, Monatshefte fur Chemie . 2001,第9期

机译：一种新型的甲基丙烯酸酯取代的氧锆簇：[Zr_3O（OR）-5（OMc）_5] _2和[Zr_3O（OR）_3（OMc）_7] _2
2. Two novel nanoscaled bismuth oxido clusters, [Bi ₃₈O ₄₅(OMc) ₂₂(C ₈H ₇SO ₃) ₂(DMSO) ₆(H ₂O) _1.5]·2.5H ₂O and [Bi ₃₈O ₄₅(HSal) ₂₂(OMc) ₂(DMSO) ₁₅(H ₂O)]·DMSO·2H ₂O [J] . Maik Schlesinger, Linda Miersch, Tobias Rüffer, Main Group Metal Chemistry . 2013,第1a2期

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3. Millimeter- and Submillimeter-Wave Observations of the OMC-2/3 Region. IV Interaction between the Outflow and the Dense Gas in the Cluster Forming Region of OMC-2 FIR 6 [J] . Yoshito SHIMAJIRI, Satoko TAKAHASHI, Shigehisa TAKAKUWA, PASJ: Publications of the Astronomical Society of Japan . 2009,第5期

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5. Application and Modifications of Ordered Mesoporous Carbon (OMC) for BTEX Removal: Characterization, Adsorption Mechanisms, and Kinetic Studies. [D] . Konggidinata, Mas Iwan. 2017

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7. Millimeter- and Submillimeter-Wave Observations of the OMC-2/3 region. IV Interaction between the Outflow and the Dense Gas in the Cluster Forming Region of OMC-2 FIR 6 [O] . 2009

机译：OMC-2 / 3区域的毫米波和亚毫米波观测。 IV OMC-2 FIR 6团簇形成区域中流出气体与浓密气体之间的相互作用
8. Far Infrared Maps of the Ridge Between OMC-1 and OMC-2 [R] . Keene, J., Smith, J., Harper, D. A., 1979

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A New Type of Methacrylate-Substituted Oxozirconium Clusters: [Zr_3O(OR)-5(OMc)_5]_2 and [Zr_3O(OR)_3(OMc)_7]_2

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