A one-pot synthesis of alkyl acylcarbamodithioates from acid chlorides, thiols, and ammonium thiocyanate

摘要

An efficient synthesis of alkyl acylcarbamodithioates by reaction of acid chlorides with ammonium thiocyanate in the presence of thiols is described. The unusually large values of ~5J_(FH) = 12-15 Hz, observed for alkyl (2-fluorobenzoyl)carbamodithioates provide information about Ar-C-N-H torsion in these compounds.