Tuning the mechanical properties of SWNT/Nylon 6,10 composites with flexible spacers at the interface

摘要

We have prepared nylon 6,10 nanocomposites using functionalized single wall carbon nanotubes and our interfacial in situ polycondensation method. The specific functional groups -(CH2)(n)COCl [n = 4 and 9] on the sidewalls of SWNT were designed to covalently link nanotubes to the nylon matrix via alkyl segments. The composites with functionalized SWNT show significant improvements in tensile modulus, strength, and toughness relative to nylon and nylon modified with nonfunctionalized SWNT. The alkyl linkages at the SWNTylon 6,10 interface contribute significantly to improving the toughness of the composites.