Transformations in Wrinkle Patterns: Cooperation between Nanoscale Cross-Linked Surface Layers and the Submicrometer Bulk in Wafer-Spun, Plasma-Treated Polydimethylsiloxane

摘要

We demonstrate control of the topography of strain-induced wrinkle patterns through the interplay between the bulk and the nanoscale cross-linked top layer of plasma treated, spin-coated polydimethylsiloxane (PDMS) thin films. The different morphological phases observed, varying from herringbones to caps, are in agreement with recent theoretical predictions. The cap phase exhibits short-range 3-fold-symmetric close-packed self-organization, demonstrating a bottom-up pathway toward the wafer-scale production of ordered, nanoscale patterns on surfaces.