Physico-Chemical Properties of Block Copolymers Based on Polyazoinitiator and Butylmethacrylate

摘要

Until now, by farthe largest portion of block copolymers (BCP) has been produced by liv-ing polymerization of anionically reactive monomers which ensured a narrow molar mass distribution. The alternative method of BCP synthesis by chain-radical polymerization using oligomeric thermo- or photo-initiators has not been considered feasible in view of its low selectivity (hence, lower probability of block structure formation).