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Microfluidics and rheology of dilute carbon black suspensions for in-mould coating (IMC) applications

机译:稀碳黑悬浮液的微流变性和流变学,用于模内涂层(IMC)应用

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In-mould coating (IMC) is carried out by injecting a thermosetting dilute carbon black suspension onto the surface of an injection-moulded part after the part has solidified, but while it is still in the mould. Due to the microscopic length scale of the IMC flow ( 10 - 25 mu m), a study of the slip flow and rheological properties at high shear rates of the coating liquid is critical in modelling the IMC process. A customized microslit rheometer using micrometer-sized channel gaps between 25 and 100 mu m was developed and used for that purpose. A reduced viscosity of the suspension due to slip ( or apparent slip) at the fluid - wall interface was found in the 25 mu m gap channel. Rheological equations for slit rheometers using no-slip and slip boundary conditions were used to determine the viscosity of the suspension at the microscale level. By analysing the viscosity data using the rheological equations developed, we can determine the values of the slip parameter, known as slip length. The slip boundary condition and high-shear-rate-plateau viscosity model are then applied to model the slip flow of the suspension. By including both the wall slip and high-shear-rate-plateau viscosity in the flow model, we can better predict the pressure distribution of the suspension.
机译:模具内涂层(IMC)是通过在零件固化后将热固性稀炭黑悬浮液注入到注塑零件的表面上而仍在模具中来进行的。由于IMC流动的微观长度尺度(10-25μm),在IMC过程建模中,研究涂料流在高剪切速率下的滑流和流变特性至关重要。为此,开发了一种定制的微缝流变仪,该微缝流变仪使用的微米级通道间隙在25至100μm之间。在25微米的间隙通道中,由于在流体-壁界面处的打滑(或明显的打滑)而导致的悬浮液粘度降低。使用无滑移和滑移边界条件的狭缝流变仪的流变方程用于确定悬浮液在微米水平的粘度。通过使用开发的流变方程分析粘度数据,我们可以确定滑移参数的值,称为滑移长度。然后应用滑移边界条件和高剪切速率高原粘度模型对悬浮液的滑流进行建模。通过在流动模型中同时包括壁滑和高剪切率平台粘度,我们可以更好地预测悬浮液的压力分布。

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