The effect of sodium sulphate on the hydrogen reduction process of nickel laterite ore

摘要

A series of nickel laterite ores with different calculated amounts of anhydrous sodium sulphate were prepared by physical blending or sodium sulphate solution impregnation. The reduction of the prepared nickel laterite ore by H_2 was carried out in a fluidised-bed reactor with provisions for temperature and agitation control, and the magnetic separation of the reduced ore was performed using a Davis tube magnetic separator. The mineralogical properties of the raw laterite ore, reduced ore and magnetic concentrate were characterised using ICP, TG-DSC, N_2 adsorption, X-ray diffraction and optical microscopy. The catalytic activity of sodium sulphate was also studied by using Hydrogen temperature-programed reduction. The experimental results indicate that Na_2SO_4 could overcome the kinetic problems faced by the laterite ore and that it exhibited noticeable catalytic activity only if the temperature reached at least 750 °C This high temperature accelerated the crystal phase transition of the silicate minerals and increased the utilisation of H_2. In comparing the results from the two different methods for adding Na_2. SO_4, the nickel content and recovery of the magnetic concentrate were increased by using the impregnation method rather than the physical blending method and the increasing amount of sodium sulphate assisted in the further beneficiation of nickel. The partial pressure of H_2 and the reducing time also affected the reduction process of the iron oxides. The results of the microscopic study indicated that the formation of a Fe-S solid solution, which was derived from the SO_2 sulphide reduction of FeO, was conducive to mass transfer and accelerated the coalescence of metallic ferronickel particles. For the nickel laterite ore, under the synergistic effect of sodium sulphate and hydrogen, a nickel content and nickel recovery of 6.38% and 91.07% were obtained, respectively, with high product selectivity.