Carbon and oxygen isotope constraints on fluid sources and fluid-wallrock interaction in regional alteration and iron-oxide-copper-gold mineralisation, eastern Mt Isa Block, Australia

摘要

The source of metasomatic fluids in iron-oxide-copper-gold districts is contentious with models for magmatic and other fluid sources having been proposed. For this study, delta~(18)O and delta ~(13)C ratios were measured from carbonate mineral separates in the Proterozoic eastern Mt Isa Block of Northwest Queensland, Australia. Isotopic analyses are supported by petrography, mineral chemistry and cathodoluminescence imagery. Marine meta-carbonate rocks (ca. 20.5 per thousand delta~(18)O and 0.5 per thousand delta~(13)C calcite) and graphitic meta-sedimentary rocks (ca. 14 per thousand delta~(18)O and -18 per thousand delta~(13)C calcite) are the main supracrustal reservoirs of carbon and oxygen in the district. The isotopic ratios for calcite from the cores of Na-(Ca) alteration systems strongly cluster around ll per thousand delta~(18)O and -7 per thousand delta ~(13)C, with shifts towards higher delta~(18)O values and higher and lower delta~(13)C values, reflecting interaction with different hostrocks. Na-(Ca)-rich assemblages are out of isotopic equilibrium with their metamorphic hostrocks, and isotopic values are consistent with fluids derived from or equilibrated with igneous rocks. However, igneous rocks in the eastern Mt Isa Block contain negligible carbon and are incapable of buffering the delta~(13)C signatures of CO_2-rich metasomatic fluids associated with Na-(Ca) alteration. In contrast, plutons in the eastern Mt Isa Block have been documented as having exsolved saline CO_2-rich fluids and represent the most probable fluid source for Na-(Ca) alteration. Intrusion-proximal, skarn-like Cu-Au orebodies that lack significant K and Fe enrichment (e.g. Mt Elliott) display isotopic ratios that cluster around values of 1 l per thousand delta~(18)O and -7 per thousand delta~(13)C (calcite), indicating an isotopically similar fluid source as for Na-(Ca) alteration and that significant fluid-wallrock interaction was not required in the genesis of these deposits. In contrast, K- and Fe-rich, intrusion-distal deposits (e.g. Ernest Henry) record significant shifts in delta~(18)O and delta~(13)C towards values characteristic of the broader hostrocks to the deposits, reflecting fluid-wallrock equilibration before mineralisation. Low temperature, low salinity, low delta~(18)O (<10 per thousand calcite) and CO_2-poor fluids are documented in retrograde metasomatic assemblages, but these fluids are paragenetically late and have not contributed significantly to the mass budgets of Cu-Au mineralisation.