Apatite nodules as an indicator of depositional environment and ore genesis for the Mesoproterozoic Broken Hill-type Gamsberg Zn-Pb deposit, Namaqua Province, South Africa

摘要

Nodules consisting of fluorapatite are concentrated as a discrete band in the polymetallic sulfide ore of the Gamsberg deposit in central Bushmanland, South Africa. Their shape, zonal features, and geochemistry, in particular rare earth element (REF) abundances, are similar to authigenic francolite concretions that precipitate during diagenesis in organic-rich muds. As a result, the apatite nodules are regarded as primary. The nodules have a strong lithostratigraphic control, occurring at the transition of siliciclastic-hosted pyrite-sphalerite-graphite mineralization to calc-silicate-hosted pyrrhotite-sphalerite mineralization. Mineralogical and chemical evidence indicates that this transition also corresponds to a paleo-redox boundary that separates sediments deposited under oxygen-deficient conditions from those that developed in a more oxygenated environment. The apatite nodules can morphologically and chemically clearly be distinguished from coarse apatite grains that occur in oxide-facies iron formations strati-graphically above the ore horizon. However, similar REE profiles and in particular positive Eu anomalies in both types of apatite are indicative of a close genetic relationship between the two units and favor a common hydrothermal origin of the P. The contrasting morphologies and chemical signatures of the two occurrences can rather be attributed to differences in behavior of the phosphates during precipitation within the contrasting host sediments (chemical versus fine-grained clastic). Taking modern phosphorites as an analogue, these results are used to postulate a genetic model for the deposition of the sulfide ore and associated iron formations. The model envisages differentiation of the depositional basin into oxygen-deficient basin facies hosting the sulfide ore and oxygenated shelf facies, which are composed of manganiferous iron formations. The intimate association of sedimentary apatite with base metal sulfides indicates that basin conditions were conducive to the precipitation of both phases. This relationship might act as a potential exploration guide in similar basins elsewhere.