Synthesis and structure of the binuclear and mononuclear complexes Co-2(mu-OH2)(2)(mu-OOCBut)(2)(Hdmpz)(4)[OS(O)(2)CF3](2)center dot 2THF and Co(Hdmpz)(2)(MeCN)(2)(OH2)(2)[OS(O)(2)CF3](2)center dot THF (Hdmpz=3,5-dimethylpyrazole)

摘要

The reaction of Co-2(mu-OOCBUt)(2)(Hdmpz)(4)(MeCN)(2)[OS(O)(2)CF3](2) (Hdmpz=3,5-dimethylpyrazole) with water in THF at room temperature gave the binuclear and mononuclear complexes Co2(mu-OH2)(2)(mu-OOCBUt)(2)(Hdmpz)(4)[OS(O)(2)CF3](2).2THF and Co(Hdmpz)(2)(MeCN)(2)(OH2)(2)[OS(O)(2)CF3](2).THF, which were characterised using X-ray diffraction analysis. [References: 8]