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High-temperature fixed points in the range 1150℃ to 2500℃ using metal-carbon eutectics

机译:使用金属-碳共晶的高温固定点在1150℃至2500℃的范围内

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摘要

The melting and freezing plateaus of three metal-carbon eutectic alloys, cobalt-carbon, iridium-carbon and rhenium-carbon, were observed by radiation thermometry for the first time, and their repeatability evaluated. The observed melting temperatures were 1324℃, 2290℃ and 2474℃, respectively. A small dependence of the freezing temperature on the cooling rate was observed for the cobalt-carbon eutectic. Six metal-carbon eutectic points have previously been reported by the present authors: these, with their melting temperatures, are iron-carbon (1153℃), nickel-carbon (1329℃), palladium-carbon (1492℃), rhodium-carbon (1657℃), platinum-carbon (1738℃), and ruthenium-carbon (1953℃). These nine fixed-point temperatures cover the range from the copper point to 2500℃. The evaluated melting-point repeatabilities (standard deviations) were generally better than 0.1℃. The metal-carbon eutectic points seem to be a promising way of realizing fixed points for practical calibration of radiation thermometers. The two fixed points above 2500 K in particular are potentially useful for thermodynamic temperature determination based on thermal radiation, as well as for radiometry and photometry.
机译:首次通过辐射测温法观察了钴-碳,铱-碳和rh-碳这三种金属-碳共晶合金的熔化和冻结平稳期,并评估了其重复性。观察到的熔融温度分别为1324℃,2290℃和2474℃。对于钴碳共晶,观察到冷冻温度对冷却速率的较小依赖性。作者先前已经报道了六个金属-碳共晶点:它们的熔化温度分别是铁-碳(1153℃),镍-碳(1329℃),钯-碳(1492℃),铑-碳。 (1657℃),铂碳(1738℃)和钌碳(1953℃)。这九个定点温度涵盖从铜点到2500℃的范围。评估的熔点重复性(标准偏差)通常优于0.1℃。金属-碳共晶点似乎是为辐射温度计的实际校准实现固定点的一种有前途的方式。高于2500 K的两个固定点尤其可用于基于热辐射的热力学温度确定以及辐射测定和光度测定。

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