Fourier transform infrared emission spectra of MgH and MgD

摘要

High resolution Fourier transform infrared emission spectra of MgH and MgD have been recorded.The molecules were generated in an emission source that combines an electrical discharge with a high temperature furnace.Several vibration-rotation bands were observed for all six isotopomers in the X ~2SIGMA~+ ground electronic state:v=1->0 to 4->3 for ~(24)MgH,v=1->0 to 3->2 for ~(25)MgH and ~(26)MgH,v=1->0 to 5->4 for ~(24)MgD,v=1->0 to 4->3 for ~(25)MgD and ~(26)MgD.The new data were combined with the previous ground state data,obtained from diode laser vibration-rotation measurements and pure rotation spectra,and spectroscopic constants were determined for the v=0 to 4 levels of ~(24)MgH and the v=0 to 5 levels of ~(24)MgD.In addition,Dunham constants and Born-Oppenheimer breakdown correction parameters were obtained in a combined fit of the six isotopomers.The equilibrium vibrational constants (omega_e) for ~(24)MgH and ~(24)MgD were found to be 1492.776(7) cm~(-1) and 1077.298(5) cm~(-1),respectively,while the equilibrium rotational constants (B_e) are 5.825523(8) cm~(-1) and 3.034344(4) cm~(-1).The associated equilibrium bond distances (r_e) were determined to be 1.729721(1) A for ~(24)MgH and 1.729 157(1) A for ~(24)MgD.