Critical loads of acidity for surface waters in south-central Ontario, Canada: regional application of the Steady-State Water Chemistry (SSWC) model

摘要

Critical loads of acidity and the amount by which these critical loads are exceeded by atmospheric deposition (termed "exceedances") were estimated for 1469 lakes from five regions in south-central Ontario, Canada, using single lake chemistry measurements and sulphur deposition data for the period 1976-1999. Based on the Steady-State Water Chemistry (SSWC) model, four of the five regions had low critical loads, which is consistent with the underlying geology (silicate bedrock) and the thin glacial soils in these regions. Sulphur deposition in the study area showed a clear downward trend over the time period, with a decrease of approximately 50% to current levels of approximately 44 meq.m(-2).year(-1). As a result of the declining deposition, the portion of lakes with critical load exceedances has dropped substantially, from 74-82% in the four sensitive regions in 1976 to 11-26% in 1999. The pentile critical load is typically used as a regional target to account for uncertainties, but also to ensure that a sufficient percentage of lakes are protected (95%). This suggests that further reductions in emissions are required to reduce depositions to approximately 34 meq.m(-2).year(-1) (11 kg S.ha(-1).year(-1)) to prevent critical load exceedance.