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Effect of gas hydrates melting on seafloor slope instability

机译:天然气水合物熔融对海底斜坡失稳的影响

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摘要

We present a theoretical study of the thermodynamic chemical equilibrium of gas hydrate in soil by taking into account the influence of temperature, pressure, pore water chemistry, and the mean pore size distribution. The model uses a new formulation based on the enthalpy form of the law of conservation of energy. The developed model shows that due to a temperature and pressure increase, hydrates may dissociate at the top of the hydrate occurrence zone to ensure a chemical equilibrium with the surrounding bulk water. This original result confirms what has been already shown through experiments. The second part of the paper presents an application of the model through a back-analysis of the giant Storegga Slide on the Norwegian margin. Two of the most important changes during and since the last deglaciation (hydrostatic pressure due to the change of the sea level and the increase of the sea water temperature) were considered in the calculation. Simulation results show that melting of gas hydrate due to the change of the gas solubility can be at the origin of a retrogressive failure initiated at the lower part of the Storegga slope. Once again, the developed model leads to predictions, which are supported by laboratory experiment results, but contradictory to previous interpretations and beliefs considering that hydrate dissociation occurs only at the bottom of the gas hydrate stability zone.
机译:通过考虑温度,压力,孔隙水化学和平均孔径分布的影响,我们对土壤中水合天然气的热力学化学平衡进行了理论研究。该模型使用基于能量守恒定律的焓形式的新公式。所开发的模型表明,由于温度和压力的升高,水合物可能在水合物出现区的顶部解离,以确保与周围的大量水保持化学平衡。原始结果证实了实验已经显示的结果。本文的第二部分通过对挪威边缘的巨型Storegga Slide的反向分析介绍了该模型的应用。在计算中考虑了最后一次冰消期间和之后的两个最重要的变化(由于海平面变化和海水温度升高引起的静水压力)。模拟结果表明,由于气体溶解度的变化而引起的天然气水合物的熔化可能是在斯托格加斜率下部引起的逆向破坏的起点。再次,开发的模型可以得出预测结果,这些预测结果得到实验室实验结果的支持,但与先前的解释和观点相反,因为水合物的解离仅发生在天然气水合物稳定区的底部,因此与先前的解释和观点相反。

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