Activation of Silicon Bonds by Fluoride Ion in the Organic Synthesis in the New Millennium: A Review

摘要

Recent advances in the fluoride ion mediated reactions of Si-H, Si-C, Si-O, Si-N, Si-P bonds containing silanes are described. Application of silicon bonds activation by fluoride ion in the syntheses of different types of organic compounds is discussed. A new mechanism, based on quantum chemical calculations, is presented. The literature data published from January 2001 to December 2004 are included in this review.