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Advances in properties and biodegradability of continuous, immicisible, biodegradable, polymer blends

机译:连续,不可模仿,可生物降解的聚合物共混物的性能和可生物降解性的进展

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A series of blends consisting of polylactic acid (PLA) and aliphatic succinate polyester (Bionolle#3000) have been prepared. The results of the mechanical property investigation have shown that using more than 20 wt% Bionolle#3000 can significantly increase the toughness of the PLA, increase the elongation at break (more than 200%) and increase the impact strength (more than 70 J/m). These properties were not significantly affected by the aging behavior of PLA for more than two months. DMA results show that Biol#3000 reduces the elastic modulus of the blends between -15 deg C and 60 deg C. Soil degradation rates of the PLA/Bio#3000 blends also increase with increasing Bio#3000 content. However, for the blends with less than 30 wt% of Bio#3000, the degradation rates do not significantly increase. Enzymatic degradation rates of the blends are higher than for those of the two polymers, and these rates increase with increasing PLA content. Composing biodegradation rates increase with increasing Bio#3000 content.
机译:已经制备了由聚乳酸(PLA)和脂肪族琥珀酸酯聚酯(Bionolle#3000)组成的一系列共混物。力学性能研究的结果表明,使用超过20 wt%的Bionolle#3000可以显着提高PLA的韧性,增加断裂伸长率(超过200%)并提高冲击强度(超过70 J / m)。这些特性不受PLA超过两个月的老化行为的显着影响。 DMA结果表明,Biol#3000在-15摄氏度和60摄氏度之间降低了掺混物的弹性模量。PLA/ Bio#3000掺混物的土壤降解率也随着Bio#3000含量的增加而增加。然而,对于具有少于30wt%的Bio#3000的共混物,降解速率没有显着提高。共混物的酶降解速率高于两种聚合物的酶降解速率,并且这些速率随PLA含量的增加而增加。合成生物降解率随Bio#3000含量的增加而增加。

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