Synthetic resins as designable supports for metal-based chemistry: the issue of their nanomorphology and molecular accessibility

摘要

Macromolecular cross-linked ligands containing pyridyl pendant groups are characterized by a combination of inverse steric exclusion chromatography, ESR and NMR spectrometries in water and methanol. On the basis of the relevant results, methanol is seen to be clearly the best swelling agent and it is chosen as medium for Cu-II coordination. [References: 26]