Isothermal vapor-liquid equilibrium data for the binary mixture difluoromethane (HFC-32)+ethyl fluoride (HFC-161) over a temperature range from 253.15K to 303.15K

摘要

Isothermal vapor-liquid equilibrium data of difluoromethane (HFC-32) + ethyl fluoride (HFC-161) mixture in the range of temperatures from 253.15. K to 303.15. K have been measured in the wide range of compositions. The experimental method used for this work is the single-cycle type. Using Peng-Robinson (PR) equation of state, combined with the first Modified Huron-Vidal (MHV1) mixing rule and Wilson model, the vapor-liquid equilibrium data are correlated. The correlation results have a good agreement with the experiment results. The average absolute vapor composition deviation is within 0.0125, and its largest absolute deviation of the vapor composition is 0.0568; the average relative pressure deviation is within 0.76% and its largest relative pressure deviation is 2.87%. In addition, the results reveal that there is no azeotrope in the binary system, and their temperature glides are small.