Long-term spatial and temporal variation of CO2 partial pressure in the Yellow River, China

摘要

Carbon transport in river systems is an important component of the global carbon cycle. Most rivers of the world act as atmospheric CO2 sources due to high riverine CO2 partial pressure (pCO(2)). By determining the pCO(2) from alkalinity and pH, we investigated its spatial and temporal variation in the Yellow River watershed using historical water chemistry records (1950s-1984) and recent sampling along the mainstem (2011-2012). Except the headwater region where the pCO(2) was lower than the atmospheric equilibrium (i.e. 380 mu atm), river waters in the remaining watershed were supersaturated with CO2. The average pCO(2) for the watershed was estimated at 2810 +/- 1985 mu atm, which is 7-fold the atmospheric equilibrium. As a result of severe soil erosion and dry climate, waters from the Loess Plateau in the middle reaches had higher pCO(2) than that from the upper and lower reaches. From a seasonal perspective, the pCO(2) varied from about 200 mu atm to >30 000 mu atm with higher pCO(2) usually occurring in the dry season and lower pCO(2) in the wet season (at 73% of the sampling sites), suggesting the dilution effect of water. While the pCO(2) responded exponentially to total suspended solids (TSS) export when the TSS concentration was less than 100 kg m(-3), it decreased slightly and remained stable if the TSS concentration exceeded 100 kg m(-3). This stable pCO(2) is largely due to gully erosion that mobilizes subsoils characterized by low organic carbon for decomposition. In addition, human activities have changed the pCO(2) dynamics. Particularly, flow regulation by dams can diversely affect the temporal changes of pCO(2), depending on the physiochemical properties of the regulated waters and adopted operation scheme. Given the high pCO(2) in the Yellow River waters, large potential for CO2 evasion is expected and warrants further investigation.